Hardness (calcium)
Reference: West, T. S., DSC, Ph.D., Complexometry with EDTA and Related Reagents, 3rd ed., p. 46, 164 (1969).

Originally described as water's capacity to precipitate soap, hardness is one of the most frequently determined qualities of water. It is a composite of the calcium, magnesium, strontium and barium concentrations in a sample. The current practice is to assume total hardness refers to the calcium and magnesium concentrations only.

Completely dehardened water, resulting from sodium zeolite or other suitable ion exchange treatment, is required for various processes-including power generation, printing and photo finishing, pulp and paper manufacturing, and food and beverage processing. Hard water can cause scale formation on heat exchange surfaces resulting in decreased heat transfer and equipment damage.

The Titrimetric Method. This method is specific for calcium hardness. The EGTA titrant in alkaline solution is employed with zincon indicator. Results are expressed as ppm (mg/L) CaCO3.

Shelf-life. 8 months. Although the reagent itself is stable, the end point indicator has a limited shelf-life. We recommend stocking quantities that will be used within 7 months.
 

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