Hydrogen peroxide is a strong oxidizing agent with a variety of uses. It is commercially available as a liquid in various concentrations. Applications include the treating of industrial effluents and domestic waste, and as a disinfectant in aseptic packaging.
The Colorimetric Methods. CHEMetrics offers products based on the
thiocyanate
reagent and the DDPDtm
reagent.
The Thiocyanate method consists of ammonium
thiocyanate and ferrous iron in acid solution. Hydrogen peroxide oxidizes
ferrous iron to the ferric state, resulting in the formation of a red thiocyanate
complex. Chlorine will not interfere with this method. Ferric iron will
interfere.Results are expressed as ppm (mg/L) H2O2.
The DDPDtm method is derived from the DPD method. It offers greater sensitivity and fewer interferences than the thiocyanate method. Hydrogen peroxide reacts with DDPD in the presence of potassium iodide to form a blue reaction product. Results are expressed as ppm (mg/L) H2O2.
The Titrimetric Method employs ceric sulfate as the titrant and ferroin
as the end point indicator. A
color change from green to orange signals the end of the titration.
Results are expressed as percent (%) H2O2.
The Ceric Sulfate Go-No-Go Method. This pass/fail hydrogen
peroxide test was developed as an efficacy test for hydrogen peroxide based
disinfecting solutions with an MEC (Minimum Effective Concentration) of
6.0+/-1.0%.
The kit includes a precision pipetting device that is used to dispense sample
into a reagent solution(ceric sulfate and ferroin) contained in a vial. An
orange color in the vial indicates that the hydrogen peroxide concentration is
greater than 6.0%. A blue or green color in the vial indicates that the hydrogen
peroxide concentration is less than 6.0%.